Is this tubing flexible and durable enough for use in a peristaltic pump, where rollers compress the tube to pump liquids?

Yes, that is what I use it for. It is important that the peristaltic pump head you are using is capable of accommodating this size of tubing as pump heads come in a range of sizes.

Can this be used to repair a coffee maker? The existing hose is food grade red silicone high temperature.

The silicone tube can work in -50°C to 200°C (-58°F to 392°F) high temperature. It could be used to a coffee maker.

What is the difference between this silicone tubing and a vinyl tubing? I want to use it to bleed the brakes on my car? Which one easier to use?

The silicone tubing and a vinyl tubing are both non-toxic and the working pressure: 30 PSI. If you want to use on the low pressure working, both of them can be used. But the working temperature of silicone tubing is much higher than vinyl, and long service,durable.

3/8" ID Silicon Tubing, JoyTube Food Grade Silicon Tubing 3/8" ID x 1/2" OD 10 Feet High Temp Pure Silicone Hose Tube for Home Brewing Winemaking

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